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Pyrrolidine-2-carboxylic acid (L-Proline) as an enantioselective catalyst

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A recent Synlett “Spotlight” focuses on the use of L-proline as an enantioselective catalyst in a number of carbon-carbon bond forming reactions.  Examples of the aldol reaction, Michael reaction, Mannich reaction, a-amination of ketones with azodicarboxylates, and the Robinson annulation are included.  (Synlett, 2003, (4), 582-583).